Point G is the centroid of △ABC if and only if GA+GB+GC=0, or equivalently, for every reference point O in the plane, OG=31(OA+OB+OC).
Why is it true?
If equal unit masses are placed at the three vertices A, B, and C, the vectors GA, GB, and GC represent the pulls toward each vertex from G; their sum is 0 precisely when G is the center of mass.
Proof sketch
Let M be the midpoint of side BC. Since M bisects BC, the two vectors MB and MC have equal length and opposite directions, so MB+MC=0. By the triangle rule from G through M, we have GB+GC=(GM+MB)+(GM+MC)=2GM.
By the median property of △ABC, the centroid G lies on the median AM and divides it in a 2:1 ratio from the vertex, meaning GA=−2GM.
Adding the two relations yields GA+GB+GC=−2GM+2GM=0. Finally, for any point O, writing GA=OA−OG (and similarly for B and C) gives (OA+OB+OC)−3OG=0, or OG=31(OA+OB+OC).